Published papers
by Hiromi Matsuhashi
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2022
Synthesis of solid acid catalysts of MgO-Al2O3 mixed oxide containing oxyanions by thermal decomposition of anion-exchanged hydrotalcites
Hiromi Matsuhashi, Catal. Surv. Asia, DOI:10.21203/rs.3.rs-2068442/v1.
Synthesis of Highly Active Solid Base Catalysts of SrO-ZrO2 and SrO-SiO2 by Solid-Liquid Interface Reactions of Hydrated Strontium Hydroxide with Metal Alkoxides
Hiromi Matsuhashi, Top. Catal., DOI:10.1016/j.cattod.2022.05.043.
Synthesis of a Solid Base Catalyst of MgO Modified with ZnO Formed from Zinc(II) Acetylacetonate
Hiromi Matsuhashi, Catal. Res., DOI:10.21926/cr.2202015.
光触媒反応の教材の開発
松橋 博美, 菊地友佳子, 北海道教育大学紀要(自然科学編), 72(2), 1-13 (2022)
2021
Synthesis of SrO-Al2O3 Solid Base Catalysts from Strontium Hydroxide and Aluminum Alkoxide by a Solid-Liquid Interface Reaction
Hiromi Matsuhashi, Asako Iwamoto, Misaho Sasaki, Kana Yoshida, Hirofumi Aritani, J. Jpn. Petro. Inst., 64(2), 103-111 (2021).
2020
Comparison of the base catalytic activity of MgO prepared by thermal decomposition of hydroxide, basic carbonate, and oxalate under atmospheric conditions
Michiko Kitagawa, Nana Ishida, Erika Yoshino, Hiromi Matsuhashi, Res. Chem. Intermed., 46 (7), 3703-3715 (2020).
Synthesis of Solid Base Catalyst of BaO-Al2O3 Binary Oxide by Solid Liquid Interface Reaction of Hydrated Barium Hydroxide with Aluminum Alkoxide
Hiromi Matsuhashi, Kohki Sato, Sayaka Misu, Kana Yoshida, J. Jpn. Petro. Inst., 63 (1), 20-27 (2020).
2019
Evaluation of the base strength of solid base catalysts by temperature-programmed desorption using propylene as a probe molecule
Hiromi Matsuhashi, Takuya Soma, Sayaka Misu, Current Top. Catal., 14, 19-24 (2019).
2018
2017
Formation of Ethylene Using Commercially Available Zeolites and Application to Teaching Material (Japanese)
H. Matsuhashi, Y. Kikuchi, T. Ito, A. Hayashi, 理科教育学研究, 57 (3), 293-299 (2017).
2016
Synthesis of Highly Active Solid Base Catalyst of Calcium Oxide Covered With Thin Layer of Titanium oxide
Hiromi Matsuhashi and Daich Funaki, J. Jpn. Petro. Inst., 59(1), 24-30 (2016).
2015
Preparation of active MgO by short-time thermal decomposition of Mg(OH)2
Michiko Kitagawa, Sayaka Misu, Jun Ichikawa, Hiromi Matsuhashi, Res. Chem. Intermed., 41 (12), 9463-9473 (2015).
2014
2013
Effect of Sulfation Using Sulfate Salt Impregnation Method on Acidity of Cobalt Oxide
Hiromi Matsuhashi, Hitoshi Taniguchi, Misako Hirai, Keita Yamamoto, Junpei Suzuki, J. Jpn. Petro. Inst., 56 (6), 381-386 (2013)
2012
Preparation of a novel solid base catalyst of CaO covered with
SiO2
Hiromi Matsuhashi, Anna Kawamura,Catal.
Today, 185, 236-240 (2012).
2011
Application of Solid Bases of MgO anf CaO Covered with Al2O3 in
Alkylation of Malonates
Yuhki Sakamoto, Hiromi
Matsuhashi, Hideo Nakamura,
J. Jpn. Petrol. Inst., 54,
385-389 (2011)
High Temperature-Tolerant Solid Acid of Zirconia Supported on Calcium
Oxide
HIromi Matsuhashi, Ryo Tabata, J. Jpn. Petrol.
Inst., 54, 272-274 (2011)
Synthesis of a water tolerant solid base of CaO covered with
Al2O3
Hiromi Matsuhashi, Tetsuro Fujita, Catal.
Today, 164, 131-134 (2011).
2010
Preferential oligomerization of isobutene in a mixture of isobutene
and 1-butene over sodium-modified 12-tungstosilicic acid supported on
silica
Jin Zhang, Mitsuru Kanno, Jiao Zhang, Ryuichiro Ohnishi, Kakeru
Toriyabe, Hiromi Matsuhashi, Yuichi Kamiya, J. Mol. Catal.
A:Chemical, 326, 107 112 (2010) .
Friedel-Crafts Acylation of Anisole with Phthalic Anhydride Catalyzed
by Solid Superacid of Sulfated Zirconia
Hideo Nakamura, Naoko Tanaka, and Hiromi
Matsuhashi, , J.
Jpn. Petro. Inst., 53(5), 276-281 (2010).
Surface Base Sites of MgO Covered With Al2O3: XANES Analysis of Al and Mg
K-edges
Hiromi Matsuhashi, Koji Nagashima, Nobuaki Naijo, and Hirofumi. Aritani,
Top. Catal.,
53, 659-663
(2010).
2009
Characterization of Sulfated Zirconia Prepared Using Reference
Catalysts and Application to Several Model Reactions, Hiromi Matsuhashi, Hideo
Nakamura, Tatsumi Ishihara, Shinji Iwamoto, Yuichi Kamiya, Junya
Kobayashi, Yoshihiro Kubota, Takashi Yamada, Takeshi Matsuda, Koichi
Matsushita, Kazuyuki Nakai, Hiroyasu Nishiguchi, Masaru Ogura,
Noriyasu Okazaki, Satoshi Sato, Ken-ichi Shimizu, Tetsuya Shishido,
Seiji Yamazoe, Tatsuya Takeguchi, Keiichi Tomishige, Hiromi
Yamashita, Miki Niwa and Naonobu Katada, Appl. Catal. A: Gen.,
360, 89-97
(2009).
Synthesis of Novel Solid Base of MgO Covered with Metal Oxides,
Hiromi Matsuhashi, Top. Catal., 52,
828-833 (2009).
2008
2007
Increase in the number of acid sites of a H-ZSM5 zeolite during the
dehydration of ethanol, Isao Takahara, Masahiro Saito,
Hiromi Matsuhashi, Megumu Inaba, and Kazuhisa Murata, Catal. Lett., 113(3-4), 82-85 (2007).
meta-Stannic acid as an effective support for the preparation of
sulfated and tungstated stannias, Makoto Hino, Satoshi Takasaki,
Satoshi Furuta, Hiromi
Matsuhashi and Kazushi Arata,
Appl. Catal. A: General, 321,
147-154 (2007).
2006
Adsorption and desorption of small molecules for the characterization
of solid acids Hiromi
Matsuhashi and Kazushi Arata,
Catalysis Surveys from Asia, 10,
1-7 (2006).
Abstract
A solid acid of tungsta-niobia more active than aluminosilicates for
decompositions of cumene, ethylbenzene, and toluene, Makoto Hino,
Mitsuhiko Kurashige, Hiromi
Matsuhashi and Kazushi Arata,
Appl. Catal. A: General, 310, 190-193 (2006). Abstract
Biodiesel fuel production with solid amorphous-zirconia catalysis in
fixed bed reactor, Satoshi Furuta, Hiromi
Matsuhashi and Kazushi Arata,
Biomass and Bioenergy, 30,
870-873 (2006).
Abstract
The surface structure of sulfated zirconia: Studies of XPS and
thermal analysis, Makoto Hino, Mitsuhiko Kurashige, Hiromi Matsuhashi and Kazushi
Arata, Thermochimica Acta, 441,
35-41(2006).
Abstract
Determination of Relative Acid Strength and Acid Amount of Solid
Acids by Ar Adsorption, Hiromi
Matsuhashi and Ayumi Futamura,
Catal. Today ,
111, 338-342
(2006).
Abstract
Synthesis of a ceramic acid of tungstated stannia more active than
aluminosilicates for the esterification of n-octanoic acid with
methanol, Makoto Hino, Satoshi Takasaki, Satoshi, Furuta,
Hiromi Matsuhashi, and Kazushi Arata, Catal.Commun. , 7, 162-165 (2006).
Abstract
Synthesis of a Ceramic Acid of Tungstated Alumina More Active Than
Silica-Alumina for Decompositions of Cumene, Ethylbenzene, and
Toluene, Makoto Hino, Hiromi
Matsuhashi, and Kazushi Arata,
Catal. Lett.,
107, 161-163
(2006).
Abstract
2005
Reaction of Linear, Branched, and Cyclic Alkanes Catalyzed by
Bronsted and Lewis Acids on H-Mordenite, H-Beta, and Sulfated
Zirconia, Takemi Wakayama and Hiromi
Matsuhashi, J.
Mol. Catal. A, J. Mol. Catal. A: ,
239, 32-40
(2005).
Abstract
2004
Biodiesel fuel production with solid amorphous zirconia catalysis in
fixed bed reactor under atmospheric pressure, Satoshi Furuta,
Hiromi Matsuhashi, and Kazushi Arata, Catal.
Commun. , 5, 721-723
(2004).
Abstract
Effect of preparation conditions on platinum metal dispersion and
turnover frequency of several reactions over platinum-supported on
alumina catalysts, Hiromi
Matsuhashi, Satoru Nishiyama, Hiroshi
Miura, Koichi Eguchid, Koji Hasegawa, Yasuo Iizuka, Akira Igarashi,
Naonobu Katada, Junya Kobayashi, Takashi Kubota, Tohru Mori, Kazuyuki
Nakai, Noriyasu Okazaki, Masatoshi Sugioka, Takashi Umeki, Yoshiteru
Yazawa and Daling Lu, Appl. Catal, A:
General, 272, 329-338
(2004).
Abstract
Catalytic action of sulfated tin oxide for etherification and
esterification-comparison with sulfated zirconia, Satoshi Furuta,
Hiromi Matsuhashi, and Kazushi Arata, Appl. Catal,
A: General, 269, 187-191
(2004).
Abstract
Distinction of Acid-type on Solid Acid Surface by Comparison of
Adsorption Heats of Nitrogen and Argon, Hiromi Matsuhashi, Keiko
Yamagata, and Kazushi Arata, Chem.
Lett., 2004, 554-555. Abstract, PDF
Measurement of the Relative Acid Strength and Acid Amount of Solid
Acids by Argon Adsorption, Hiromi
Matsuhashi, and Kazushi Arata,
Phys. Chem. Chem. Phys., in press.
Abstract
Influence of Calcination Temperature on Surface Acidity of the Solid
Superacid of Sulfated Alumina, Hiromi
Matsuhashi, Daishi Sato, and Kazushi
Arata, React. Kinet. Catal.
Lett., 81, 183 (2004). Abstract
2003
Isomerization of cycloheptane,cyclooctane,and cyclodecane catalyzed
by sulfated zirconia - comparison with open-chain alkanes, Daishi
Satoh, Hiromi Matsuhashi, Hideo Nakamura and Kazushi Arata, Phys. Chem. Chem. Phys.,
5, 4343-4349
(2003). Abstract,
PDF
Synthesis of Solid Superacids and Their Activites for Reactions of
Alkanes, Kazushi Arata, Hiromi
Matsuhashi, Makoto Hino, and Hideo
Nakamura, Catal. Today, 81,
17-30 (2003).
Abstract
Isomerization of Cycloheptane to Methylcyclohexane and Cyclooctane to
Ethylcyclohexane Catalyzed by Sulfated Zirconia, Daishi Satoh,
Hiromi Matsuhashi, Hideo Nakamura, and Kazushi Arata, Catal. Lett., 89 , 105-107 (2003).
Abstract
2002
2001
Catalytic Activities of Calcined Iron Sulfates for Hydrocracking of
Model Compounds of Coal, Hiromi
Matsuhashi, Keiko Asari, and Kazushi
Arata, Energy & Fuels, 15,
1523-1527 (2001).
Abstract, PDF
Measurement of Heat of Argon Adsorption for The Evaluation of
Relative Acid Strength of Some Sulfated Metal Oxides and H-type
Zeolites, Hiromi Matsuhashi, Takae Tanaka, and Kazushi Arata, J. Phys. Chem. B ,
105, 9669-9671
(2001). Abstract,
PDF
The Preparation of Solid Superacid of Sulfated Tin Oxide with Acidity
Higher Than Sulfated Zirconia and Its Applications to Aldol
Condensation and Benzoylation, Hiromi
Matsuhashi, Hidenori Miyazaki, Yuuki
Kawamura, Hideo Nakamura, and Kazushi Arata, Chem. Mater. , 13, 3038-3042 (2001).
Abstract,
PDF
Effects of the Proton Content of ZSM-5 and the Amount of Pt on the
Hydrodesulfurization Activity of Pt/ZSM-5, T. Kurosaka, M. Sugioka,
and H. Matsuhashi, Bull. Chem. Soc.
Jpn., 74, 757-763 (2001).
Abstract
The Preparation of Solid Superacid of Sulfated Tin Oxide with Acidity
Higher Than Sulfated Zirconia, H.
Matsuhashi, H. Miyazaki, and K. Arata,
Chem. Lett.,
2001, 452-453.
Abstract
Formation of Superbase Sites on Alkaline Earth Oxides by Dorping of
Alkali Metals, Hiromi
Matsuhashi, Masakazu Oikawa, and Kazushi
Arata, Langmuir,
16, 8201 (2000).
Abstract
Formation of Acid Sites in Orderd Pores of FMS-16 by Modification
with Sulfated Zirconia, Hiromi
Matsuhashi, Michiko Tanaka, Hideo
Nakamura, and Kazushi Arata, Appl. Catal.
A: General , 208, 1-5 (2001). Abstract
2000
Mukaiyama Aldol Reaction of 1-Trimethylsilyloxy-1-cyclohexene with
Benzaldehyde over Solid Superacids with Preferential Syn Selectivity,
Hideo Nakamura, Hiromi
Matsuhashi,and Kazushi Arata,
Synlett,
2000, 668-670.
Abstract
Temperature Programmed Desorption of Argon for Evaluation of Surface
Acidity of Solid Superacids, Hiromi
Matsuhashi and Kazushi Arata,
Chem. Commun,
2000, 387-388.
Abstract