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硫酸化ジルコニアプロジェクト ホームページ 触媒学会講師派遣講習内容 |
このウィンドウを閉じる 2022 Synthesis of solid acid catalysts of MgO-Al2O3 mixed oxide containing oxyanions by thermal decomposition of anion-exchanged hydrotalcites Hiromi Matsuhashi, Catal. Surv. Asia, DOI:10.21203/rs.3.rs-2068442/v1. Synthesis of Highly Active Solid Base Catalysts of SrO-ZrO2 and SrO-SiO2 by Solid-Liquid Interface Reactions of Hydrated Strontium Hydroxide with Metal Alkoxides Hiromi Matsuhashi, Top. Catal., DOI:10.1016/j.cattod.2022.05.043. Synthesis of a Solid Base Catalyst of MgO Modified with ZnO Formed from Zinc(II) Acetylacetonate Hiromi Matsuhashi, Catal. Res., DOI:10.21926/cr.2202015. 光触媒反応の教材の開発 松橋 博美, 菊地友佳子, 北海道教育大学紀要(自然科学編), 72(2), 1-13 (2022) 2021 Synthesis of SrO-Al2O3 Solid Base Catalysts from Strontium Hydroxide and Aluminum Alkoxide by a Solid-Liquid Interface Reaction Hiromi Matsuhashi, Asako Iwamoto, Misaho Sasaki, Kana Yoshida, Hirofumi Aritani, J. Jpn. Petro. Inst., 64(2), 103-111 (2021). 2020 Comparison of the base catalytic activity of MgO prepared by thermal decomposition of hydroxide, basic carbonate, and oxalate under atmospheric conditions Michiko Kitagawa, Nana Ishida, Erika Yoshino, Hiromi Matsuhashi, Res. Chem. Intermed., 46 (7), 3703-3715 (2020). Synthesis of Solid Base Catalyst of BaO-Al2O3 Binary Oxide by Solid-Liquid Interface Reaction of Hydrated Barium Hydroxide with Aluminum Alkoxide Hiromi Matsuhashi, Kohki Sato, Sayaka Misu, Kana Yoshida, J. Jpn. Petro. Inst., 63 (1), 20-27 (2020). 2019 Evaluation of the base strength of solid base catalysts by temperature-programmed desorption using propylene as a probe molecule Hiromi Matsuhashi, Takuya Soma, Sayaka Misu, Current Topics in Catalysis, 14, 19-24 (2019). 2018 2017 市販のゼオライトによるエチレンの生成と教材化 松橋博美, 菊地友佳子, 伊藤崇由, 林 昭宏, 理科教育学研究, 57 (3), 293-299 (2017). 2016 Synthesis of Highly Active Solid Base Catalyst of Calcium Oxide Covered With Thin Layer of Titanium oxide Hiromi Matsuhashi and Daich Funaki, J. Jpn. Petro. Inst., 59(1), 24-30 (2016). 2015 Preparation of active MgO by short-time thermal decomposition of Mg(OH)2 Michiko Kitagawa, Sayaka Misu, Jun Ichikawa, Hiromi Matsuhashi, Res. Chem. Intermed., 41 (12), 9463-9473 (2015). 2014 2013 Effect of Sulfation Using Sulfate Salt Impregnation Method on Acidity of Cobalt Oxide Hiromi Matsuhashi, Hitoshi Taniguchi, Misako Hirai, Keita Yamamoto, Junpei Suzuki, J. Jpn. Petro. Inst., 56 (6), 381-386 (2013) 2012 Preparation of a novel solid base catalyst of CaO covered with SiO2 Hiromi Matsuhashi, Anna Kawamura, Catal. Today, 185, 236-240 (2012) 2011 Application of Solid Bases of MgO anf CaO Covered with Al2O3 in Alkylation of Malonates Yuhki Sakamoto, Hiromi Matsuhashi, Hideo Nakamura, J. Jpn. Petrol. Inst., 54, 385-389 (2011) High Temperature-Tolerant Solid Acid of Zirconia Supported on Calcium Oxide HIromi Matsuhashi, Ryo Tabata, J. Jpn. Petrol. Inst., 54, 272-274 (2011) Synthesis of a water tolerant solid base of CaO covered with Al2O3 Hiromi Matsuhashi, Tetsuro Fujita, Catal. Today, 164, 131-134 (2011). 2010 Preferential oligomerization of isobutene in a mixture of isobutene and 1-butene over sodium-modified 12-tungstosilicic acid supported on silica Jin Zhang, Mitsuru Kanno, Jiao Zhanf, Ryuichiro Ohnishi, Kakeru Toriyabe, Hiromi Matsuhashi, Yuichi Kamiya, J. Mol. Catal. A: Chemical, 326, 107-1212 (2010). Friedel-Crafts Acylation of Anisole with Phthalic Anhydride Catalyzed by Solid Superacid of Sulfated Zirconia Hideo Nakamura, Naoko Tanaka, and Hiromi Matsuhashi, , J. Jpn. Petro. Inst., 53(5), 276-281 (2010). Surface Base Sites of MgO Covered With Al2O3: XANES Analysis of Al and Mg K-edges Hiromi Matsuhashi, Koji Nagashima, Nobuaki Naijo, and Hirofumi. Aritani, Top. Catal., 53, 659-663 (2010). 2009 Characterization of Sulfated Zirconia Prepared Using Reference Catalysts and Application to Several Model Reactions Hiromi Matsuhashi, Hideo Nakamura, Tatsumi Ishihara, Shinji Iwamoto, Yuichi Kamiya, Junya Kobayashi, Yoshihiro Kubota, Takashi Yamada, Takeshi Matsuda, Koichi Matsushita, Kazuyuki Nakai, Hiroyasu Nishiguchi, Masaru Ogura, Noriyasu Okazaki, Satoshi Sato, Ken-ichi Shimizu, Tetsuya Shishido, Seiji Yamazoe, Tatsuya Takeguchi, Keiichi Tomishige, Hiromi Yamashita, Miki Niwa and Naonobu Katada,Appl. Catal. A: Gen., 360, 89-97 (2009). Synthesis of Novel Solid Base of MgO Covered with Metal Oxides Hiromi Matsuhashi, Top. Catal., 52, 828-833 (2009). 2008 2007 Pretreatment of MFI Type Zeolite with Ethylene to Enhance Their Catalytic Activities for Dehydration of Ethanol Isao Takahara, Masahiro Saito, Hiromi Matsuhashi, Hirofumi Aritani, Megumu Inaba,and KazuhiroMurata, J. Jpn. Petro.Inst., 50(4), 227-228 (2007). Increase in the number of acid sites of a H-ZSM5 zeolite during the dehydration of ethanol Isao Takahara, Masahiro Saito, Hiromi Matsuhashi, Megumu Inaba, and Kazuhisa Murata, Catal. Lett., 113, 82-85 (2007). meta-Stannic acid as an effective support for the preparation of sulfated and tungstated stannias Makoto Hino, Satoshi Takasaki, Satoshi FurutaHiromi Matsuhashi and Kazushi Arata, Appl. Catal. A: General, 321, 147-154 (2007). 2006 Adsorption and desorption of small molecules for the characterization of solid acids Hiromi Matsuhashi and Kazushi Arata, Catalysis Surveys from Asia, 10, 1-7 (2006). A solid acid of tungsta-niobia more active than aluminosilicates for decompositions of cumene, ethylbenzene, and toluene Makoto Hino, Mitsuhiko Kurashige, Hiromi Matsuhashi and Kazushi Arata, Appl. Catal. A: General, 310, 190-193 (2006). Biodiesel fuel production with solid amorphous-zirconia catalysis in fixed bed reactor Satoshi Furuta, Hiromi Matsuhashi and Kazushi Arata, Biomass and Bioenergy, 30, 870-873 (2006). The surface structure of sulfated zirconia: Studies of XPS and thermal analysis, Makoto Hino, Mitsuhiko Kurashig Hiromi Matsuhashi and Kazushi Arata, Thermochimica Acta, 441, 35-41(2006). Determination of Relative Acid Strength and Acid Amount of Solid Acids by Ar Adsorption, Hiromi Matsuhashi and Ayumi Futamura, Catal. Today , 111, 338-342 (2006). Synthesis of a ceramic acid of tungstated stannia more active than aluminosilicates for the esterification of n-octanoic acid with methanol, Makoto Hino, Satoshi Takasaki, Satoshi, Furuta, Hiromi Matsuhashi, and Kazushi Arata, Catal.Commun. , 7, 162-165 (2006). Synthesis of a Ceramic Acid of Tungstated Alumina More Active Than Silica-Alumina for Decompositions of Cumene, Ethylbenzene, and Toluene, Makoto Hino, Hiromi Matsuhashi, and Kazushi Arata, Catal. Lett., 107, 161-163 (2006). 2005 Reaction of Linear, Branched, and Cyclic Alkanes Catalyzed by Br?0?2nsted and Lewis Acids on H-Mordenite, H-Beta, and Sulfated Zirconia, Takemi Wakayama and Hiromi Matsuhashi, J. Mol. Catal. A, J. Mol. Catal. A: , 239, 32-40 (2005). 2004 Biodiesel fuel production with solid amorphous zirconia catalysis in fixed bed reactor under atmospheric pressure, Satoshi Furuta, Hiromi Matsuhashi, and Kazushi Arata, Catal. Commun. , 5, 721-723 (2004). Effect of preparation conditions on platinum metal dispersion and turnover frequency of several reactions over platinum-supported on alumina catalysts, Hiromi Matsuhashi, Satoru Nishiyama, Hiroshi Miura, Koichi Eguchid, Koji Hasegawa, Yasuo Iizuka, Akira Igarashi, Naonobu Katada, Junya Kobayashi, Takashi Kubota, Tohru Mori, Kazuyuki Nakai, Noriyasu Okazaki, Masatoshi Sugioka, Takashi Umeki, Yoshiteru Yazawa and Daling Lu, Appl. Catal, A: General, 272, 329-338 (2004). Catalytic action of sulfated tin oxide for etherification and esterification-comparison with sulfated zirconia, Satoshi Furuta, Hiromi Matsuhashi, and Kazushi Arata, Appl. Catal, A: General, 269, 187-191 (2004). Distinction of Acid-type on Solid Acid Surface by Comparison of Adsorption Heats of Nitrogen and Argon, Hiromi Matsuhashi, Keiko Yamagata, and Kazushi Arata, Chem. Lett., 2004, 554-555. Measurement of the Relative Acid Strength and Acid Amount of Solid Acids by Argon Adsorption, Hiromi Matsuhashi, and Kazushi Arata, Phys. Chem. Chem. Phys., 6, 2529-2533 (2004). Influence of Calcination Temperature on Surface Acidity of the Solid Superacid of Sulfated Alumina, Hiromi Matsuhashi, Daishi Sato, and Kazushi Arata, React. Kinet. Catal. Lett., 81, 183 (2004). 2003 Isomerization of cycloheptane,cyclooctane,and cyclodecane catalyzed by sulfated zirconia - comparison with open-chain alkanes, Daishi Satoh, Hiromi Matsuhashi, Hideo Nakamura and Kazushi Arata, Phys. Chem. Chem. Phys., 5, 4343-4349 (2003). Synthesis of Solid Superacids and Their Activites for Reactions of Alkanes, Kazushi Arata, Hiromi Matsuhashi, Makoto Hino, and Hideo Nakamura, Catal. Today, 81, 17-30 (2003). Isomerization of Cycloheptane to Methylcyclohexane and Cyclooctane to Ethylcyclohexane Catalyzed by Sulfated Zirconia, Daishi Satoh, Hiromi Matsuhashi, Hideo Nakamura, and Kazushi Arata, Catal. Lett., 89 , 105-107 (2003). 2002 2001 Catalytic Activities of Calcined Iron Sulfates for Hydrocracking of Model Compounds of Coal, Hiromi Matsuhashi, Keiko Asari, and Kazushi Arata, Energy & Fuels, 15, 1523-1527 (2001). Measurement of Heat of Argon Adsorption for The Evaluation of Relative Acid Strength of Some Sulfated Metal Oxides and H-type Zeolites, Hiromi Matsuhashi, Takae Tanaka, and Kazushi Arata, J. Phys. Chem. B , 105, 9669-9671 (2001). The Preparation of Solid Superacid of Sulfated Tin Oxide with Acidity Higher Than Sulfated Zirconia and Its Applications to Aldol Condensation and Benzoylation, Hiromi Matsuhashi, Hidenori Miyazaki, Yuuki Kawamura, Hideo Nakamura, and Kazushi Arata, Chem. Mater. , 13, 3038-3042 (2001). Effects of the Proton Content of ZSM-5 and the Amount of Pt on the Hydrodesulfurization Activity of Pt/ZSM-5, T. Kurosaka, M. Sugioka, and H. Matsuhashi, Bull. Chem. Soc. Jpn., 74, 757-763 (2001). The Preparation of Solid Superacid of Sulfated Tin Oxide with Acidity Higher Than Sulfated Zirconia, H. Matsuhashi, H. Miyazaki, and K. Arata, Chem. Lett., 2001, 452-453. Formation of Superbase Sites on Alkaline Earth Oxides by Dorping of Alkali Metals, Hiromi Matsuhashi, Masakazu Oikawa, and Kazushi Arata, Langmuir, 16, 8201 (2000). Formation of Acid Sites in Orderd Pores of FMS-16 by Modification with Sulfated Zirconia, Hiromi Matsuhashi, Michiko Tanaka, Hideo Nakamura, and Kazushi Arata, Appl. Catal. A: General , 208, 1-5 (2001). 2000 Mukaiyama Aldol Reaction of 1-Trimethylsilyloxy-1-cyclohexene with Benzaldehyde over Solid Superacids with Preferential Syn Selectivity, Hideo Nakamura, Hiromi Matsuhashi,and Kazushi Arata, Synlett, 2000, 668-670. Temperature Programmed Desorption of Argon for Evaluation of Surface Acidity of Solid Superacids, Hiromi Matsuhashi and Kazushi Arata, Chem. Commun, 2000, 387-388. |